To study surfaces we use a variety of Analytical tools:

Collaborators: Professor David Allara of Penn State, Professor R. Mark Wightman (UNC) and Professor Leslie Sombers (NC State)

Publications from this Project:

1.         Roberts, J. G., Moody, B. P., McCarty, G. S. & Sombers, L. A. Specific Oxygen-Containing Functional Groups on the Carbon Surface Underlie an Enhanced Sensitivity to Dopamine at Electrochemically Pretreated Carbon Fiber Microelectrodes. Langmuir (2010).

2.         Takmakov, P. et al. Carbon Microelectrodes with a Renewable Surface. Analytical Chemistry 82, 2020-2028 (2010).

3.         Daniel, T. A., Uppili, S., McCarty, G. & Allara, D. L. Effects of molecular structure and interfacial ligation on the precision of Cu-bound alpha,omega-mercaptoalkanoic acid "molecular ruler" stacks. Langmuir 23, 638-648 (2007).

Surface Chemistry, Microscopy and Spectroscopy

The understanding of surfaces and how they interact with their environment can advance understanding and functionality of many systems. Understanding surface properites is especially important in nanofabrications and chemical and biological sensors. For example by tailoring surface properties cells can be directed or patterned on a surface (example shown below).

To study surfaces we use a variety of Analytical tools:
Infrared Spectroscopy (example spectra are shown to right)
X-Ray Photospectroscopy
Atomic Force Microscopy
Ellipsometry
Contact Angle

Raman spectroscopy and electrochemistry can also be used.